Zinc bromide

Zinc bromide

Names
IUPAC name Zinc bromide
Other names Zinc(II) bromide, Zinc dibromide
Identifiers
CAS Number	7699-45-8 Y
ChemSpider	22790 Y
Jmol 3D model	Interactive image
PubChem	24375
RTECS number	ZH1150000
UNII	OO7ZBU9703 Y
InChI InChI=1S/2BrH.Zn/h2*1H;/q;;+2/p-2 Y Key: VNDYJBBGRKZCSX-UHFFFAOYSA-L Y InChI=1/2BrH.Zn/h2*1H;/q;;+2/p-2 Key: VNDYJBBGRKZCSX-NUQVWONBAG
SMILES Br[Zn]Br
Properties
Chemical formula	ZnBr2
Molar mass	225.198 g/mol
Appearance	white crystalline powder hygroscopic
Density	4.20 g/cm3 (20 °C) 4.22 g/cm3 (25 °C)
Melting point	394 °C (741 °F; 667 K)
Boiling point	697 °C (1,287 °F; 970 K)
Solubility in water	311 g/100 mL (0 °C) 447 g/100 mL (20 °C) 538 g/100 mL (100 °C)
Solubility	very soluble in alcohol, ether, acetone, tetrahydrofuran
Refractive index (nD)	1.5452
Vapor pressure	{{{value}}}
Related compounds
Other anions	Zinc fluoride, Zinc chloride, Zinc iodide
Other cations	Cadmium bromide, Mercury(II) bromide, Calcium bromide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Zinc bromide (ZnBr₂) is an inorganic compound with the chemical formula ZnBr₂. It is a colourless salt that shares many properties with zinc chloride (ZnCl₂), namely a high solubility in water forming acidic solutions, and solubility in organic solvents. It is hygroscopic and forms a dihydrate ZnBr₂ · 2H₂O.

Production

ZnBr₂ · 2H₂O is prepared by treating zinc oxide or zinc metal with hydrobromic acid.

ZnO + 2 HBr + H₂O → ZnBr₂ · 2H₂O

The anhydrous material can be produced by dehydration of the dihydrate with hot CO₂ or by reaction of zinc metal and bromine.

Structure

Crystalline ZnBr₂ adopts the same structure as ZnI₂: four tetrahedral Zn centers share three vertices to form “super-tetrahedra” of nominal composition {Zn₄Br₁₀}²⁻, which are linked by their vertices to form a three-dimensional structure. The dihydrate ZnBr₂ · 2H₂O also has a usual structure and should be described as Zn(H₂O)₆ Zn₂Br₆, where the Zn₂Br₆²⁻ ion has bromine bridges linking the two zinc atoms. A similar structure is found in the dimeric form of aluminium bromide (Al₂Br₆).

Gaseous ZnBr₂ is linear in accordance with VSEPR theory with a Zn-Br bond length of 221 pm.

Uses

Zinc bromide is used in the following applications:

• In organic chemistry as a Lewis acid.

• It is the electrolyte in the zinc bromide battery.

• In oil and natural gas wells, solutions containing zinc bromide are used to displace drilling mud when transitioning from the drilling phase to the completion phase or in well workover operations. The extremely dense brine solution gives the fluid its weight of 20 pounds/gallon, which makes it especially useful in holding back flammable oil and gas particles in high pressure wells. However, the high acidity and osmolarity cause corrosion and handling problems. Crews must be issued slicker suits and rubber boots because the fluid is so dehydrating.

• Zinc bromide solutions can be used as a transparent shield against radiation. The space between two glass panes is filled with a strong aqueous solution of zinc bromide with a very high density, to be used as a window on a hot cell. This type of window has the advantage over lead glass in that it will not darken as a result of exposure to radiation. All glass will darken slowly over time due to radiation, however this is especially true in a hot cell, where exceptional levels of radiation are present. The advantage of an aqueous salt solution is that any radiation damage will last less than a millisecond, so the shield will undergo self-repair.

Safety

Safety considerations are similar to those for zinc chloride, for which the toxic dose for humans is 3–5 g.

See also

• Zinc chloride
• Zinc fluoride
• Zinc iodide
• Cadmium bromide