Kopp's law

File:Hermann Kopp 01.jpg

Hermann Franz Moritz Kopp

Kopp's law can refer to either of two relationships discovered by the German chemist Hermann Franz Moritz Kopp (1817–1892).

1. Kopp found "that the molecular heat capacity of a solid compound is the sum of the atomic heat capacities of the elements composing it; the elements having atomic heat capacities lower than those required by the Dulong–Petit law retain these lower values in their compounds."
2. In studying organic compounds, Kopp found a regular relationship between boiling points and the number of CH₂ groups present.

Kopp–Neumann law

The Kopp–Neumann law, named for Kopp and Franz Ernst Neumann, states that the specific heat C per unit mass (in J·kg⁻¹·K⁻¹) for alloys can be calculated from the following equation:

$C=\sum_{i=1}^N(C_i \cdot f_i)$ ,

where N is the total number of alloy constitutents, and C_i and f_i denote the specific heat and mass fraction of the i-th constituent.

References

• Frederick Seitz, The Modern Theory of Solids, McGraw-Hill, New York, USA, 1940, ASIN: B000OLCK08